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在固体氧化物燃料电池的萨马里注射的Ceria-NiRh催化剂中揭示硫耐受性机制
Yue Bao1, Junseok Kim1,2, Subrina Islam1
1Department of Chemical Engineering, University of Utah, Salt Lake City, Utah 84112, United States.
Journal of the American Chemical Society
|February 19, 2026
概括
固体氧化物燃料电池 (SOFC) 中的硫中毒受到新的NiRh催化剂的缓解. 这些催化剂表现出优越的硫耐受性和自我清洁性能,提高了燃料的灵活性和耐用性.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 催化剂是一种催化剂.
背景情况:
- 硫中毒是燃料灵活固体氧化物燃料电池 (SOFC) 中耐用阳极催化剂的主要障碍.
- 在SOFC催化剂中支持硫耐受性的原子尺度机制尚不清楚.
研究的目的:
- 为了研究 NiRh 催化剂的行为,支持在添加的 (SDC-NiRh) 上,以提高硫耐受性.
- 揭示SOFC阳极催化剂中抗硫和自我清洁的基本机制.
主要方法:
- 在操作条件下对硫金属相互作用的现场观察.
- 催化剂表面物种及其动态演变的特征.
- 使用SDC-NiRh和SDC-Ni催化剂对SOFC进行性能测试.
主要成果:
- 在Ni催化剂 (SDC-NiRh) 中的Rh结合抑制了持续的Ni-S物种的形成,并促进了硫的自我清洁.
- 与SDC-Ni.Rh相比,SDC-Ni.Rh表现出增强的吸水和表面反应性.
- 具有SDC-NiRh的SOFC显示在H2S暴露下超过3倍的输出功率和较低的阻力.
结论:
- 该SDC-NiRh催化剂表现出优越的硫耐受性和自我清洁能力.
- 了解这些机制指导未来燃料灵活和耐硫SOFC阳极催化剂的设计.
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