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由真菌酶驱动的沉聚合:捕获雌激素化学物质以阻止蔬菜污染

Qian Yin¹, Wei Dai¹, Chunxia Liu¹

¹Anhui Province Key Lab of Farmland Ecological Conservation and Nutrient Utilization, College of Resources and Environment, Anhui Agricultural University, Hefei 230036, China.

Journal of hazardous materials

|February 20, 2026

概括

这项研究表明,Trametes versicolor laccase酶如何通过促进其聚合来消除水中的雌激素化学物质 (ECs). 这种绿色方法显著降低了可食用植物部位的EC,最大限度地降低了饮食风险.

科学领域:

环境科学环境科学
生物技术是生物技术.
食品安全食品安全

背景情况:

食品中的雌激素污染构成了全球健康问题.
蔬菜作物可以通过根部吸收积累雌激素化学物质 (ECs).
制定有效的补救策略对于食品安全至关重要.

研究的目的:

为了研究Trametes versicolor laccase在水中ECs的根系修复中的有效性.
评估酶驱动的聚合物对EC消散和植物吸收的影响.
评估这种酶处理对减少通过饮食暴露于ECs的潜力.

主要方法:

使用Trametes versicolor laccase催化水根球中的四个EC (E1,E2,EE2,BPA) 的降水聚合.
在36小时的时间内,与laccase治疗组和laccase缺乏对照组进行了EC消散率和植物积累的比较.
分析了高分子量,疏水性沉物的形成及其对EC生物可用性的影响.

主要成果:

酸盐处理显著加速了根球中的EC消散,使效率从32.18-61.36%提高到91.07-100.00%.
酶聚合形成了高分子量,疏水沉物,降低了EC根度18.65-74.04%,并阻碍了转移到可食用的部分.
消散速率常数增加了7.26-17.31倍,而根吸收速率常数 (k2) 被调制,表明EC生物可用性降低.

结论:

特拉梅特斯 (Trametes versicolor laccase) 有效地驱动了超分子聚合和ECs的封存到根球内的无毒沉物中.
这种酶方法提供了一种环保和高效的方法来阻止蔬菜作物的EC生物可用性.
这项研究强调了一种有希望的策略,以尽量减少与产品中雌激素污染相关的饮食风险.

关键词:

雌激素化学品的使用情况菌的乳糖酶是一种真菌.沉聚合物的聚合.草根修复草根修复蔬菜作物蔬菜作物

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