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双位吸附在纸张的高扩张中
Jantinus Wisman1,2, Marjolein N van der Linden2,3, Thomas Anijs3
1Physics of Interfaces and Nanomaterials and MESA+ Institute, University of Twente, P.O. Box 217, Enschede 7500 AE, Netherlands.
Langmuir : the ACS journal of surfaces and colloids
|February 20, 2026
概括
湿度会导致纸纤维在相对湿度上升时线性扩张. 这种纸张扩张发生在两个阶段,表明纸张结构内有不同的水吸附点.
科学领域:
- 材料科学 材料科学 材料科学
- 表面科学是一门学科.
- 聚合物科学 聚合物科学
背景情况:
- 湿度显著影响纸张的性能,影响印刷和包装等应用.
- 纸纤维吸收的水会导致其膨胀 (水力或液体膨胀).
研究的目的:
- 用原子力显微镜研究纸张的超平面膨胀.
- 分析相对湿度和纸纤维膨胀之间的关系.
- 了解纸张膨胀和收缩的动力学和机制.
主要方法:
- 原子力显微镜 (AFM) 用于高分辨率的平面外测量.
- 在一系列相对湿度水平下进行的实验.
- 吸附异热量测量以量化水的吸收.
- 扩张/收缩的时间分辨率监控,具有毫秒分辨率.
主要成果:
- 观察到相对湿度和外平面纤维扩张之间的线性相关性.
- 吸附等热量数据符合古根海姆-安德森-德布尔模型.
- 水填充纤维间的孔隙有助于增加重量,但不会扩展到外平面.
- 纸张膨胀和收缩动力学遵循双倍指数函数,表明有两个吸附点.
结论:
- 纸纤维的膨胀与相对湿度成正比.
- 古根海姆-安德森-德布尔模型准确地描述了纸上的水吸附.
- 独特的吸水机制会影响纸张的尺寸变化.
- AFM为纸张在不同湿度下的纳米尺度行为提供了关键的见解.
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