对于内在可拉伸的有机光伏来说,结合聚合物的相对分子-mesoscale进化
Wenkai Zhong1,2, Guillaume Freychet3,4, Gregory M Su5,6
1Institute of Polymer Optoelectronic Materials and Devices, Guangdong Basic Research Center of Excellence for Energy and Information Polymer Materials, State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou, China. wkzhong@scut.edu.cn.
拉伸合聚合物薄膜揭示了两阶段的结构变化,影响了它们在柔性电子中的性能. 了解这种演变是坚固,高性能可拉伸设备的关键.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物科学 聚合物科学
- 凝聚物质物理学 凝聚物质物理学
背景情况:
- 结合聚合物薄膜由于其光电子性质和灵活性,对可拉伸电子有很大的希望.
- 机械强度和高设备性能是开发这些材料的关键挑战.
- 了解压力下的结构演变对于优化性能至关重要.
研究的目的:
- 为了研究结合聚合物薄膜在单轴变形过程中的多尺度结构演变.
- 建立半导体聚合物变形的机械框架.
- 为机械坚固,高性能可拉伸电子产品提供设计原则.
主要方法:
- 使用了一套全面的X射线光谱和散射技术.
- 在单轴变形过程中研究的结构变化.
- 与材料特性相关的结构适应.
主要成果:
- 在变形过程中发现了两阶段的形态反应.
- 观察到初始的聚合物链对齐和结晶体破坏.
- 确定了连续链方向,在更高的压力下具有链内扭转.
结论:
- 变形引起的结构变化决定了应力消散,光学吸收和光伏性能.
- 建立了理解聚合物变形的机制框架.
- 提供了先进的可拉伸电子产品的设计原则.
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