化引起的可塑性和金属玻璃的强化
Yingjie Zhang1, Jinyue Wang1, Leqing Liu2
1State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing, China.
Advanced science (Weinheim, Baden-Wurttemberg, Germany)
|February 23, 2026
概括
亚Tg化通过创建纳米级化学异质性来增强金属玻璃的可塑性. 这种工程结构增加了150%以上的强度和压缩性塑料应变.
科学领域:
- 材料科学 材料科学 材料科学
- 金工业是金工业的一个方面.
- 纳米技术 纳米技术
背景情况:
- 金属玻璃通常由于自由体积的消灭而在化时变得脆弱.
- 局部松散包装区域 (LLPRs) 对于金属玻璃的可塑性至关重要.
研究的目的:
- 挑战金属玻璃中火诱导的脆化模式.
- 通过亚Tg化来证明同时增强强度和可塑性.
- 为了研究炼金属玻璃中可塑性背后的结构机制.
主要方法:
- 基于Zr的金属玻璃的Tg以下化.
- 结构和机械性能的实验分析.
- 原子模拟用于探测原子级别的行为.
主要成果:
- 亚Tg化增加了超过150%的压缩性塑料应变.
- 化诱导的纳米化学异质性是由Ni-Cu排斥驱动的.
- 原子模拟揭示了局部密集区域 (LDPR) 作为剪切转换场所的出现.
结论:
- 在金属玻璃中,化引起的脆化并不是不可避免的.
- 具有LLPR和LDPR的异质结构可以维持可塑性.
- 化学异质性的战略工程为增强金属玻璃性能提供了一个新的设计范式.
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