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Updated: Feb 26, 2026

Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance
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Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance

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设计原子精确和坚固的共价有机框架,以提高/酸盐的吸收:具有和没有氧基组的结构

Qianyi Zuo1, Xin Zheng1,2, Aokun Jia1

  • 1MOE Key Laboratory of Resources and Environmental Systems Optimization, College of Environmental Science and Engineering, North China Electric Power University, Beijing 102206, China. jizhuoyu@ncepu.edu.cn.

Nanoscale
|February 24, 2026
PubMed
概括

基于三烯胺的共价有机框架 (COF) 旨在有效地去除,化物和酸盐. 这些新型材料具有很高的吸附能力和可重复使用性,为环境修复提供了有希望的解决方案.

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Bromination and chlorination of aromatic rings by electrophilic aromatic substitution reactions are easily achieved, but fluorination and iodination are difficult to achieve. Fluorine is so reactive that its reaction with benzene is difficult to control, resulting in poor yields of monofluoroaromatic products. To address this, Selectfluor reagent is used as a fluorine source in which a fluorine atom is bonded to a positively charged nitrogen.
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Alkyl halides are halogen-substituted alkanes wherein one or more hydrogen atoms of an alkane is replaced by a halogen atom such as fluorine, chlorine, bromine, or iodine. The carbon atom in an alkyl halide is bonded to the halogen atom, which is sp3-hybridized and exhibits a tetrahedral shape.
Unlike alkyl halides, compounds in which a halogen atom is bonded to an sp2 -hybridized carbon atom of a carbon-carbon double bond (C=C) are called vinyl halides. Whereas aryl...
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Compared to ionic bonds, which results from the transfer of electrons between metallic and nonmetallic atoms, covalent bonds result from the mutual attraction of atoms for a “shared” pair of electrons.
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Isomers are different chemical species that have the same chemical formula. Structural isomerism of coordination compounds can be divided into two subcategories, the linkage isomers and coordination-sphere isomers.
Linkage isomers occur when the coordination compound contains a ligand that can bind to the transition metal center through two different atoms. For example, the CN− ligand can bind through the carbon atom or through the nitrogen atom. Similarly, SCN− can...
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