在用于宽温度无水燃料电池的聚胺醇膜中,协同作用的结和共价交联
Junming Dai1,2, Jianming Zhong1,2, Jinpeng Luo1,2
1State Key Laboratory of Biopharmaceutical Preparation and Delivery, Institute of Process Engineering, Chinese Academy of Sciences, Beijing, China.
Advanced science (Weinheim, Baden-Wurttemberg, Germany)
|February 24, 2026
概括
研究人员开发了一种用于质子交换膜燃料电池 (PEMFC) 的双网络膜. 这种新的膜增强了操作温度范围,减少了湿度的依赖,提高了燃料电池的性能.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 质子交换膜燃料电池 (PEMFC) 面临着运行温度范围和湿度依赖的挑战.
- 现有的膜往往需要高湿度,这限制了它们在各种条件下的应用.
研究的目的:
- 为PEMFCs开发一种新的膜架构,扩大操作温度并降低湿度灵敏度.
- 为了提高燃料电池膜的性能和稳定性.
主要方法:
- 用双网络架构制造特罗格基 (TB) 功能化的聚胺醇膜.
- 热增强的键矩阵和氨酸-无化物共价交联框架的整合.
- 膜性质的表征,包括酸吸收,质子导电性,氧化稳定性和机械强度.
主要成果:
- 双网络的TBAm-PBI-TB膜实现了高酸吸收 (469.5%) 与最小的浸出.
- 质子导电率在90°C/20%RH时达到255.5mS cm-1和在160°C (无水) 时达到264.7mS cm-1.
- 在无水条件下,一个膜电极组件 (MEA) 在30-160°C之间显示了从108.6到446.2mW cm-2的峰值功率密度,超过了Nafion 211.
结论:
- 开发的双网膜为无水燃料电池在高温下运行提供了一个有前途的解决方案.
- 该战略解决了当前PEMFC膜的关键局限性,为更广泛的应用铺平了道路.
- 证实了卓越的氧化和机械稳定性,以及运行耐用性.
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