基团对支持的碳-TiO2对质子交换膜燃料电池的活性和耐久性的影响
Su-Jin Jang1, Yi Kyeong Jung1, Jeong Han Lee1
1Korea Institute of Ceramic Engineering & Technology Jin-ju 52851 Republic of Korea lsh@kicet.re.kr ths@kicet.re.kr.
这项研究开发了用于质子交换膜燃料电池 (PEMFC) 的耐用TiO2-碳混合支持. 改性TiO2支持在膜电极组件 (MEAs) 中增强氧降解反应 (ORR) 的催化剂活性和稳定性.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 催化剂是一种催化剂.
背景情况:
- 质子交换膜燃料电池 (PEMFC) 通常在碳支上使用 (Pt) 催化剂,但碳腐蚀限制了耐用性.
- 金属氧化物-碳复合材料正在探索,以提高PEMFC的支耐用性.
研究的目的:
- 开发和评估氧空位和基基组修饰的TiO2颗粒支持Pt纳米颗粒用于PEMFC应用.
- 调查TiO2晶度对氧降解反应 (ORR) 催化剂性能的影响.
主要方法:
- 微波辅助合成不同TiO2晶度的Pt纳米粒子/TiO2-碳催化剂.
- 使用X射线衍射 (XRD),X射线光电子谱学 (XPS) 和减弱总反射 (ATR) 谱学进行了表征.
- 通过ORR活动测试和膜电极组件 (MEA) 测试进行性能评估.
主要成果:
- 未加的TiO2-碳支物显示出Ti-OH物种的存在,增强了ORR活性.
- 在 anatase TiO2 上支持的 Pt 催化剂由于强烈的金属支相互作用 (SMSI) 而表现出优越的 ORR 活性和稳定性.
- MEA测试证实了开发的催化剂的高活性和提高耐用性.
结论:
- 含有修改的TiO2 (氧空位和基) 的TiO2-碳混合支持改善了PEMFC中的Pt催化剂性能.
- 解剖酶TiO2结晶性和SMSI对于增强的氧气减少动力学和耐用性至关重要.
- 这些发现为设计先进燃料电池技术的耐用混合支持提供了洞察力.
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