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Updated: Feb 27, 2026

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
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Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

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将罗森塔尔试剂的活性扩展到环烯和烯

Marcel Eilers1, Dennis Geik1, Marc Schmidtmann1

  • 1Institut für Chemie, Carl von Ossietzky Universität Oldenburg, Postfach 2503, 26111 Oldenburg, Germany. ruediger.beckhaus@uni-oldenburg.de.

Dalton transactions (Cambridge, England : 2003)
|February 26, 2026
PubMed
概括

罗森塔尔试剂Cp2Ti ((η2-BTMSA) 与环烯反应形成环烯,这些环烯重新排列成反应性碳物种. 然后,这些碳与酸盐发生循环添加,产生酸.

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