从水性介质中高效地去除 (V) 和 (III),使用Fe-Ti-Mn/花素复合物Xerogel珠
Chunting Chen1, Junbao Liu1, Hongpeng Cao1
1School of Environmental and Material Engineering, Yantai University, Yantai 264005, China.
Gels (Basel, Switzerland)
|February 26, 2026
概括
这项研究提出了Fe-Ti-Mn/奇托桑凝珠,用于有效地从水中去除有毒物种 (As(V和As(III)). 新型复合珠具有高吸附能力和高效的再生,用于水安全应用.
科学领域:
- 环境科学 环境科学
- 材料科学 材料科学 材料科学
- 化学 化学 化学
背景情况:
- 无机物种As (V) 和As (III) 在饮用水中具有显著的毒性和致癌风险.
- 有效地去除对于全球水安全和公共健康至关重要.
- 传统的吸附剂在同时去除和固体-液体分离方面经常面临局限性.
研究的目的:
- 开发和评估一种新型的Fe-Ti-Mn/色素复合式色素珠 (FTMO/色素) 用于同时去除As (V) 和As (III).
- 为了应对与粉状吸附剂的固体液体分离相关的挑战.
- 为了研究复合珠的吸附性能,动力学和机制.
主要方法:
- 进行了批量吸附实验,以评估FTMO/奇托桑珠的性能.
- 吸附同热量用弗洛伊德利希模型进行分析.
- 用伪二阶动力模型评估了吸附动力学.
- 机械学研究探讨了物种与吸附剂表面之间的相互作用.
主要成果:
- 在25°C时,FTMO/奇托桑珠具有较高的最大吸收能力:As (III) 的22.6 mg/g和As (V) 的16.2 mg/g.
- 在24小时内达到吸附平衡,遵循伪二次动力学.
- 吸附效率受到溶液pH值和共存的阳离子的显著影响.
- 通过内部球面复合发生了As(V) 的去除,而As(III) 的去除则涉及到氧化到As(V) 之后的吸附.
结论:
- FTMO/色素复合物凝珠在同时从水中去除 (III) 和 (V) 方面非常有效.
- 吸附剂显示出出色的再生能力和运行稳定性.
- 这种材料对水处理和环境修复的实际应用具有显著的前景.
相关概念视频
Extraction: Advanced Methods
1.2K
Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
1.2K
Ion Exchange
1.4K
Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or...
1.4K
Masking and Demasking Agents
3.7K
EDTA titrations may necessitate masking and demasking agents to temporarily protect a particular metal ion in a mixture from the EDTA reaction. These agents facilitate the sequential analysis of the metal ions by forming stable complexes with some—but not all—metal ions during certain steps.
There are many masking agents, such as cyanide, fluoride, triethanolamine, thiourea, and 2,3-bis(sulfanyl)propan-1-ol (formerly 2,3-dimercapto-1-propanol), with the masking agent chosen based on...
There are many masking agents, such as cyanide, fluoride, triethanolamine, thiourea, and 2,3-bis(sulfanyl)propan-1-ol (formerly 2,3-dimercapto-1-propanol), with the masking agent chosen based on...
3.7K
Colloidal precipitates
6.6K
The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
6.6K


