基于变损伤和故障概率的固体氧化物燃料电池的长期稳定性的材料组成设计
1College of Transportation, Shandong University of Science and Technology, Qingdao 266590, China.
Materials (Basel, Switzerland)
|February 27, 2026
概括
在固体氧化物燃料电池 (SOFC) 电极中优化含量可以提高长期稳定性. 最佳的Ni范围为50-60%,可以最大限度地减少爬行损伤,这对于可靠的SOFC操作至关重要.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 机械工程 机械工程
背景情况:
- 电极降解是固体氧化物燃料电池 (SOFC) 性能下降的一个关键因素.
- 材料成分显著影响SOFC在高温下的长期稳定性.
研究的目的:
- 调查阳极和阴极材料组成对SOFC爬行损伤和故障概率的影响.
- 确定最佳的电极材料组合,以延长SOFC的使用寿命.
主要方法:
- 在SOFC中经过5万小时的运行后,分析了爬行损伤和故障概率.
- 在阳极材料中对不同 (Ni) 体积分的评估.
- 考虑在阴极组合中使用氧化 (La0.8Sr0.2MnO3 - LSM).
主要成果:
- 将Ni体积分数从30%增加到50%,可以减少爬行损伤.
- 进一步增加Ni含量 (60-70%) 导致爬虫损伤增加.
- 对于长期SOFC运行,确定了50-60%的最佳Ni体积分数.
- 较高的电化学效率LSM适用于阴极制造.
结论:
- 阳极材料中的Ni含量极大地影响机械完整性和抗爬能力.
- 对于耐用的SOFC电极,建议Ni体积分数为50-60%.
- 像LSM这样的正极材料的战略选择可以进一步提高SOFC的性能和寿命.
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