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Updated: Mar 1, 2026

Synthesis of Cyclic Polymers and Characterization of Their Diffusive Motion in the Melt State at the Single Molecule Level
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Published on: September 26, 2016

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循环双块共聚合物的结构颜色通过拓驱动的结构排序实现,并通过与组成的循环聚合物混合来调整

Jiyun Nam1, Eugene Y-X Chen1

  • 1Department of Chemistry, Colorado State University; Fort Collins, Colorado 80523, United States.

Journal of the American Chemical Society
|February 27, 2026
PubMed
概括

循环双块共聚合物 (CDC) 能够在光子膜中实现调节的结构颜色. 它们独特的循环拓驱动了快速自组装以控制着色彩,克服了高分子量聚合物的挑战.

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Characteristics and Nomenclature of Copolymers

Copolymers are the products obtained from the polymerization of multiple monomer species. So, in a polymer chain itself, there can be multiple repeating units that come from different monomers. The process of synthesizing a polymer from different monomer species is called copolymerization. When two monomers are involved, the polymer is known as a bipolymer. Polymers with three and four monomers are termed terpolymers and quaterpolymers, respectively. Figure 1 depicts the copolymerization of...
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Polymers are classified as linear or branched on the basis of their chain architecture. The polymer chains in linear polymers have a long chain-like structure with minimal to no branching at all. Even if a polymer features large substituent groups on the monomer, which appear as branches to the skeleton, it is not considered a branched polymer. A branched polymer contains secondary polymer chains that arise from the main polymer chain. The branching occurs when the polymer growth shifts from...
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Unlike ionic or small covalent molecules, polymers do not form crystalline solids due to the diffusion limitations of their long-chain structures. However, polymers contain microscopic crystalline domains separated by amorphous domains.
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