在Pb-Zn炼废物中的:特异性,稳定性和环境风险
Jie Li1, Jiemin Qin1, Zeyu Kang1
1School of Environment and Energy, Guangdong Provincial Key Laboratory of Solid Wastes Pollution Control and Recycling, South China University of Technology, Guangzhou 510006, China.
Journal of environmental sciences (China)
|March 1, 2026
概括
化废物中的 (Tl) 污染是一个主要问题. 这项研究揭示了Tl的高度和显著的生态风险,需要紧急安全处置含有Tl的污泥.
科学领域:
- 环境科学 环境科学
- 地质化学 地质化学
- 工业废物管理 工业废物管理
背景情况:
- 来自非铁金属炼的 (Tl) 污染是一个日益严重的环境问题.
- 有限的研究存在于TI的特异化和炼废物的释放,阻碍了有效的风险管理.
研究的目的:
- 调查来自中国炼厂的重金属硫化物污泥 (HMSS) 中的 Tl 物种化,分布和释放行为.
- 与其他重金属相比,评估HMSS中Tl所带来的生态风险.
主要方法:
- 使用XRD,XPS和SEM-EDS进行HMSS的表征.
- 序列提取协议以确定TL的特异化.
- 以pH值为依赖的浸出试验和风险评估代码 (RAC) 进行释放行为和生态风险评估.
主要成果:
- 在HMSS中含有高度的Tl (高达35,098.81 mg/kg),液Tl达到1127.20 mg/L.
- 在水中可提取的,嵌入石膏的和稳定的形式中发现了tl,在广泛的pH范围内释放出显著的值.
- 与Pb,Cd和 Zn.相比,Tl 的生态风险 (60.83%-67.38%) 是最高的.
结论:
- 高温水泥污染是TI污染的重要来源,带来了相当大的环境风险.
- 的高流动性和生态风险凸显了含的炼废物的专业处理和处置的迫切需要.
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