在复合水凝中,非线性弹性和过渡到宏观不可逆性
Ippolyti Dellatolas1, Thibaut Divoux2,3, Emanuela Del Gado4
1Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139, USA. ippolyti@mit.edu.
Soft matter
|March 3, 2026
概括
填充剂-水凝复合材料表现出明显的非线性行为. 在临界应变时,发生不可逆转的变化,导致永久的弹性损失,表明这些先进材料的产量.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物科学 聚合物科学
- 类风病学 类风病学 类风病学
背景情况:
- 填充剂-水凝复合材料提供了增强的机械性能和功能.
- 具有吸引力的纳米填充剂-凝相互作用显著增加线性粘弹性模块,即使在低体积分数下也是如此.
研究的目的:
- 为了研究具有吸引力的填充剂-水凝复合材料的非线性粘弹性反应.
- 为了确定导致宏观不可逆转和屈服的关键变形点.
主要方法:
- 在凝矩阵中使用有吸引力的纳米填充剂.
- 进行应变幅扫描和应力放松试验,以分析粘弹性模块 (G'和G′′).
主要成果:
- 复合材料表现出纳米填充剂诱导的硬化,但在其粘弹性反应中保持与纯水凝的定性相似性.
- 临界应变幅度触发了一个过渡,标志着改变的应力放松和不可逆转的变化.
- 确定了三个不同的模式:非线性弹性,宏观不可逆性和收益率.
结论:
- 这些复合材料的宏观不可逆转性与水凝矩阵内的键断有关.
- 该研究阐明了填充剂-水凝复合材料中复杂的非线性行为和故障机制.
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