关于阻燃矿业输送带的热解动力学和产品特性研究
Guoxiang Wen1, Jia Li1, Xiao Wang2
1School of Safety Engineering, China University of Mining and Technology, Xuzhou, Jiangsu, 221116, China; China Academy of Safety Science and Technology, Beijing, 100012, China.
Journal of environmental management
|March 4, 2026
概括
来自采矿带的阻燃 (FRR) 的热解发生在三个阶段,释放HCl和有机化合物. 这项研究阐明了FRR热解,有助于废物管理和环境风险评估.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 环境科学 环境科学
背景情况:
- 废弃的阻燃采矿输送带 (FRMB) 面临着处置方面的挑战.
- 阻燃层 (FRR) 是一个关键的组件,由于其热解产品,造成环境风险.
研究的目的:
- 系统地阐明FRR的热解动力学和产品演变.
- 为FRR热解提出一个统一的阶段分类框架.
主要方法:
- 热重力测量分析和动力模型 (无模型,适合模型,趋势受约束的动力差异演变).
- 在不同热解阶段对气态和固体残留产品的分析.
主要成果:
- FRR热解发生在三个不同的阶段 (483593 K, 593693 K, 693973 K),具有特定的激活能量.
- 主要气态产品包括化,化碳化合物,二氧化甲酸盐 (DOP),二氧化碳和芳香碳化合物.
- 固体残留物显示P,Ca和Mg的多孔性和丰富性增加,几乎完全释放.
结论:
- 建立了FRR的三阶段热解框架,详细介绍了脱化和脱碳化等反应机制.
- 了解产品演变有助于资源利用和FRR废物的环境风险评估.
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