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Updated: Mar 6, 2026

Retropinacol/Cross-pinacol Coupling Reactions - A Catalytic Access to 1,2-Unsymmetrical Diols
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Published on: April 4, 2014

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光驱 Sm 催化不对称的 基-奥莱芬 合器

Li-Ming Chen1, Drew E Tarnopol1, Sarah E Reisman1

  • 1The Warren and Katharine Schlinger Laboratory for Chemistry and Chemical Engineering, Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, United States.

Journal of the American Chemical Society
|March 4, 2026
PubMed
概括

这项研究引入了一种新型的催化方法,用于使用三二氧化物 (SmI2) 和一种性二-二) 连接剂进行对抗选择性还原性合. 这一突破使得与以前未知的催化剂SmI2进行了不对称的合成.

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