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Updated: Mar 10, 2026

Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
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Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions

Published on: July 17, 2020

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结合锁定强化硫-多环共价有机框架与不对称的电子分布的光催化有氧氧化反应

Jiani Yang1, Shihuan Gao1, Zhenyang Zhao1

  • 1College of Polymer Science and Engineering, State Key Laboratory of Advanced Polymer Materials, Sichuan University, Chengdu 610065, China.

Journal of the American Chemical Society
|March 9, 2026
PubMed
概括

研究人员使用一种新的后循环化策略开发了持久的硫-异多环共价有机框架 (COF). 这些先进的COF表现出增强的稳定性和优越的光催化活性,用于能源和合成应用.

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Photochemical Electrocyclic Reactions: Stereochemistry

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Selection Rules: Photochemical Activation
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The stereochemistry of electrocyclic reactions is strongly influenced by the orbital symmetry of the polyene HOMO. Under thermal conditions, the reaction proceeds via the ground-state HOMO.
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