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Updated: Mar 12, 2026

Highly Stereoselective Synthesis of 1,6-Ketoesters Mediated by Ionic Liquids: A Three-component Reaction Enabling Rapid Access to a New Class of Low Molecular Weight Gelators
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Published on: November 27, 2015

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非对称的 (-) - 维鲁卡罗尔总合成

Madison H Powers1, John F McCleerey1, Jeffrey W Bacon1

  • 1Department of Chemistry and Center for Molecular Discovery (BU-CMD), Boston University, Boston, Massachusetts, USA.

Angewandte Chemie (International ed. in English)
|March 11, 2026
PubMed
概括

这项研究提出了 (-) - 维鲁卡罗尔的简要合成,这是三烯宏循环的前体. 该方法克服了在使用enantioselective循环添加和循环化策略构建复杂的12,13-epoxytrichothec-9-ene核心的挑战.

关键词:
不对称的催化剂.这是一个循环加法循环.自然产品是自然产品的产品.总合成总合成在Tricho的场景里.

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