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Updated: Jun 24, 2026

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通过乙捐赠基质工程,对镜像的AEP1-中介结合

Qingyao Shu1, Yuxuan Wang1, Chaowei Shi2

  • 1Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, China.

Journal of the American Chemical Society
|March 11, 2026
PubMed
概括

这项研究引入了一种新的合成d-的方法,使用与OaAEP1酶一起的工程乙烯基捐赠基质. 这一突破促进了用于药物发现和合成生物学应用的镜像的创造.

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Olefin Metathesis Polymerization: Acyclic Diene Metathesis (ADMET)00:53

Olefin Metathesis Polymerization: Acyclic Diene Metathesis (ADMET)

Acyclic diene metathesis polymerization or ADMET polymerization involves cross-metathesis of terminal dienes, such as 1,8-nonadiene, to give linear unsaturated polymer and ethylene. As ADMET is a reversible process, the formed ethylene gas must be removed from the reaction mixture to complete the polymerization process.
Similar to cross-metathesis, ADMET also involves the formation of metallacyclobutane intermediate by [2+2] cycloaddition of one of the double bonds of a terminal diene with...