对共价有机框架的超声诱导再结晶,其结晶性大大提高
Bo Chen1,2, Xinghua Guo1,2, Xu Han1,2
1Qianwan Institute of CNITECH, Zhongchuang 1st Road, Zhongchuang Park, Qianwan New Area, Ningbo, Zhejiang 315336, China. Wangdegao@nimte.ac.cn.
概括
研究人员开发了一种简单的合成后超声波方法,以显著提高共价有机框架 (COF) 的结晶性. 这种广泛适用的策略可以在不改变合成条件的情况下增强COF材料.
科学领域:
- 材料科学 材料科学 材料科学
- 化学 化学 化学
背景情况:
- 提高共价有机框架 (COF) 的结晶性对于它们的应用至关重要.
- 目前的方法专注于合成参数,忽视了合成后的修改.
研究的目的:
- 引入一种新的,广泛适用的合成后策略,以提高COF结晶性.
- 为了证明超声波对COF晶体改善的有效性.
主要方法:
- 对预先合成的COFs进行了简单的后合成声波处理.
- 该策略在六种不同的COF上进行了测试,包括具有因胺和β-基因酶胺链接的COF.
主要成果:
- 超声波显著提高了所有测试的COF的结晶性.
- 该战略在不同的COF结构和链接类型中被证明是有效的.
结论:
- 合成后的超声波是改善COF结晶性的可行和有效方法.
- 这种方法为调整传统合成控制之外的COF特性提供了一个新的途径.
相关概念视频
Recrystallization: Solid–Solution Equilibria
4.2K
Recrystallization is a purification technique used to separate impurities from solid compounds. In this technique, no chemical reactions occur. Instead, it exploits physical properties only, specifically, the solubility differences between the desired compound and impurities, either at a single temperature or at different temperatures, and under other selected conditions. The solid-solution equilibrium (solubility equilibrium) of each component in the solution represents a binary phase...
4.2K
Crystal Growth: Principles of Crystallization
5.6K
Crystallization is a phase transformation process in which crystals are precipitated from a supersaturated solution or formed from other sources. During crystallization, atoms or molecules arrange themselves into a well-defined, rigid crystal lattice to minimize energy.
Initiating crystallization involves manipulating the concentration of the solute and the temperature of the solution. Since crystal growth occurs when the ratio of concentration and solubility of the solute in the solvent...
Initiating crystallization involves manipulating the concentration of the solute and the temperature of the solution. Since crystal growth occurs when the ratio of concentration and solubility of the solute in the solvent...
5.6K
Polymer Classification: Crystallinity
4.2K
Unlike ionic or small covalent molecules, polymers do not form crystalline solids due to the diffusion limitations of their long-chain structures. However, polymers contain microscopic crystalline domains separated by amorphous domains.
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
4.2K


