针对可吸附有机化物 (AOX) 的优化方法和素特异性规范,用于追踪消毒副产品从源头到水龙头
Florence Vélia1,2, Marie-Florence Thomas2, Carine Demelas1
1Aix Marseille Univ, LCE, Marseille, France.
Analytical and bioanalytical chemistry
|March 14, 2026
概括
饮用水中的消毒副产品 (DBPs) 构成健康风险. 这项研究优化了测量吸附性有机化物 (AOX) 的方法,显示大多数有机化物不受监测,需要对水安全进行更广泛的监测.
科学领域:
- 环境化学环境化学
- 分析化学 分析化学
- 公共卫生 公共卫生
背景情况:
- 饮用水中的消毒副产品 (DBPs) 是有毒的,并与健康问题有关.
- 目前的欧洲法规不充分监测有害的酸盐和酸盐DBPs.
- 可吸附有机化物 (AOX) 提供了DBP毒性的全面测量.
研究的目的:
- 优化和验证AOX,NPOX和素特异性AOX (AOCl,AOBr,AOI) 的分析方法.
- 评估法国饮用水分配网络中有机素的流行和物种化情况.
- 突出现行法规的局限性以及扩大DBP监测的需要.
主要方法:
- 优化关键参数:吸附效率,挥发,矩阵干扰和离子色谱.
- 对AOX,NPOX和素特异性AOX的分析方法的验证.
- 优化方法应用于法国四个配送网络的饮用水样本.
主要成果:
- 实现了AOX,NPOX,AOBr和AOI的低量化极限.
- 非可净化有机化物 (NPOX) 占总AOX的50-90% .
- 监管的THM和HAA占总AOX的很小一部分,这表明了大量未被监控的有机素.
结论:
- 优化的分析方法提供了AOX及其分量的可靠量化.
- 在法国,饮用水中含有大量未被监测的有机化合物,特别是NPOX.
- 除了THM和HAA之外,扩大DBP监测对于准确的水安全评估至关重要.
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