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甘氨胺驱动的库马林构造 (GDCC):光标记和酸宏循环的温和策略

Xiao-Fei Gao1,2, Wei Xiao1,2, Tian-Ming Tao3

  • 1jiangxi Provincial Key Laboratory of Organic Functional Molecules, Institute of Organic Chemistry, College of Chemistry and Chemical Engineering, Jiangxi Science and Technology Normal University, Nanchang, China.

Angewandte Chemie (International ed. in English)
|March 14, 2026
PubMed
概括

一种新的甘氨胺驱动的库马林构造 (GDCC) 反应使光化宏循环的高效合成成为可能. 这种无金属和无催化剂的方法为各种化学生物学应用创造了内在光循环.

关键词:
这是一种光化.甘氨酸修饰基因的修饰类结合的结合.酸接合 酸接合酸药物结合物结合物

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The reaction of weakly electrophilic aryldiazonium (also called arenediazonium) salts with highly activated aromatic compounds leads to the formation of products with an —N=N— link, called an azo linkage. This reaction, presented in Figure 1, is known as diazo coupling and occurs without the loss of the nitrogen atoms of the aryldiazonium salt. Highly activated aromatic compounds such as phenols or arylamines favor the diazo coupling reaction. The coupling generally occurs at the para...
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