瓦纳和在石油焦炭气化废渣中的发生形式演变和出动力学
Zhang Liping1, Yang Rongchao2, Geng Xuchao3
1State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Qingdao 266580, China; College of Chemistry and Chemical Engineering, China University of Petroleum, Qingdao 266580, China; Qingdao Huicheng Environmental Protection Technology Group Co., Ltd., Qingdao 266000, China.
Waste management (New York, N.Y.)
|March 14, 2026
概括
石油焦炭气化渣 (POX渣) 可以成为有价值的 (Ni) 和 (V) 金属的来源. 通过化进行脱碳,会影响金属的分布和回收,从而支持废物利用.
科学领域:
- 材料科学 材料科学 材料科学
- 环境科学 环境科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 石油焦炭气化渣 (POX渣) 是一种危险的固体废物.
- 这些渣代表了未充分利用的二次资源,用于Ni和V的回收.
- 关于POX渣价值化,特别是金属提取的研究是有限的.
研究的目的:
- 为了研究通过化脱碳对V和Ni分布和POX渣的发生的影响.
- 为了研究从化POX渣中出V和Ni的液化动力学.
- 支持从POX渣中回收Ni和V的方法的开发.
主要方法:
- 在不同温度下对POX渣进行化.
- 描述POX灰的结构和组成 (例如,核心-结构).
- 研究V和Ni物种的聚合和分布.
- 使用Avrami模型对V和Ni酸出液的动态分析.
主要成果:
- 化产生具有核心外结构的POX灰 (Si/Al核心,S/Ca外).
- 在较低的化温度下,V和Ni物种聚合成较小的颗粒.
- 较高的温度稳定了V和Ni,但没有显著改变空间分布.
- 漂水动力学遵循Avrami模型,由表面反应和扩散控制.
- 激活能量表明V从POX灰中泄漏的速度快于Ni.
结论:
- 通过化脱碳影响POX渣中的V和Ni行为.
- 该研究提供了对优化Ni和V恢复条件的见解.
- 这些发现支持从危险的POX渣渣废物中提取贵金属的技术发展.
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