压力分解和多聚合物组合进化离子型酸盐水凝在大幅度的振荡式剪切流
Changyao Liu1, Wei Yu1, Sijun Liu1
1Advanced Rheology Institute, Department of Polymer Science and Engineering, Shanghai Jiao Tong University, Shanghai, 200240, PR China; State Key Laboratory of Polyolefins and Catalysis, Shanghai Key Laboratory of Catalysis Technology for Polyolefins, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240, PR China.
Carbohydrate polymers
|March 14, 2026
概括
甲基酸盐水凝表现出复杂的流动行为. 一个新的模型揭示了网络缺陷和生存网络在压力下如何演变,有助于设计先进的生物材料.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 类风病学 类风病学 类风病学
背景情况:
- 甲基酸盐 (SA) 水凝由于多个结点,纠和网络缺陷而表现出复杂的质性质.
- 了解SA网络在大振幅振荡剪切 (LAOS) 流动期间的结构演变至关重要但具有挑战性.
研究的目的:
- 开发一种方法来分析LAOS流中的SA网络的结构组件.
- 为了解SA网络中的多重放松和应变硬化行为提出模型.
主要方法:
- 在Lissajous曲线上开发剪切停止方法.
- 关于用于网络放松分析的双拉伸指数 (DSE) 模型的建议.
- 应力强化 (SH) 模型的应用来研究生存网络行为.
主要成果:
- 在LAOS流中SA网络响应可以分为应变速率依赖的网络缺陷和应变依赖的生存网络.
- 高协会强度导致网络缺陷减少,网络存活密度更高.
- 增加的应变幅度促进了多重体组件的解离,并释放了被困的纠.
结论:
- 应力分解和SH模型的结合为SA网络结构的演变提供了洞察力.
- 这项研究阐明了SA水凝中非线性力学的微观结构起源.
- 这些发现将有助于设计具有量身定制性质的高性能多糖生物材料.
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