地下水中酸盐在管理下层补充期间的演变:从DOM特征和稳定同位素的洞察力
Congchao Xu1, Rui Li2, Weiwu Hu3
1School of Water Resources and Environment, MOE Key Laboratory of Groundwater Circulation and Environmental Evolution, China University of Geosciences (Beijing), Beijing 100083, China.
Journal of hazardous materials
|March 15, 2026
概括
管理的含水层补充 (MAR) 改变了溶解有机物 (DOM) 的特性,影响了酸盐水平. 这项研究揭示了MAR如何通过改变DOM特征和微生物活动来改变酸盐平衡,改善地下水质量.
科学领域:
- 环境科学 环境科学
- 水文地质学 水文地质学
- 生物地质化学生物地质化学
背景情况:
- 管理的含水层补充 (MAR) 对地下水管理至关重要,但其通过溶解有机物 (DOM) 对酸盐动态的影响尚不清楚.
- 了解DOM变化是管理MAR系统中酸盐污染的关键.
研究的目的:
- 调查河流诱导的MAR如何影响DOM属性,从而影响酸盐的转化.
- 在MAR条件下阐明控制酸盐源-沉平衡的机制.
- 建立一个综合框架来分析DOM驱动的酸盐变化.
主要方法:
- 水化学分析的分析方法
- 超高分辨率的DOM分子特征 (FT-ICR-MS) 的研究.
- 稳定同位素分析 (碳和)
- 微生物社区分析
- 可以解释的机器学习
主要成果:
- 马尔增强了地下水和地表水的连接,增加了地下水位,溶解氧气,溶解有机碳和酸盐.
- 重充衍生的DOM显示了改变的特性 (较低的分子量,更高的O/C,N-丰富),提高了生物可用性.
- 马尔刺激酸盐的产生 (矿化,化) 和去除 (脱化),使酸盐系统重新平衡.
- 机器学习确定了影响酸盐转换的关键DOM分子参数 (NOSC,O/C比,分子质量).
结论:
- 马尔显著改变DOM特征,推动转向更高效的酸盐转化途径.
- 一个集成的DOM-微生物-同位素框架为MAR系统中的酸盐动态提供了新的见解.
- 结果为地下水质量监管和在管理充电操作中减轻污染提供了战略.
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