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Updated: Mar 17, 2026

Preparation and Use of Carbonyl-decorated Carbenes in the Activation of White Phosphorus
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Preparation and Use of Carbonyl-decorated Carbenes in the Activation of White Phosphorus

Published on: October 3, 2014

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N-异环碳素-Ag (I) -氨酸复合物:通过密度功能理论进行全面的合成,表征和结合分析

Abdollah Neshat1, Mohammad Reza Yousefshahi1, Mahdi Cheraghi1

  • 1Department of Chemistry, Institute for Advanced Studies in Basic Sciences (IASBS), 444 Prof. Sobouti Blvd, Gava Zang, Zanjan 45137-66731, Iran.

ACS omega
|March 16, 2026
PubMed
概括

含有素连接体的银 (I) 复合物比金 (I) 复合物不那么稳定. 像PCy3和PPh2Py这样的特定配体可以稳定溶液中的阴离子银碎片,从而影响复杂的形成.

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sp3d and sp3d 2 Hybridization
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Basicity of Heterocyclic Aromatic Amines

Heterocyclic amines, where the N atom is a part of an alicyclic system, are similar in basicity to alkylamines. Interestingly, the heterocyclic amine having a nitrogen atom as part of an aromatic ring has much less basicity than its corresponding alicyclic counterpart. For this reason, as presented in Figure 1, piperidine (pKb = 2.8) is significantly more basic than pyridine (pKb = 8.8).
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Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...
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Crystal Field Theory
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