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Updated: Mar 18, 2026

Author Spotlight: Functionalizing Metal-Organic Frameworks: Advancements, Challenges, and the Power of Post-Synthetic Ligand Exchange
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聚态驱动的协调几何工程,用于促进Cu-pyrazolate链中的酸盐电还原

Zhanning Liu1, Shanna An1, Qingzhong Xue1

  • 1School of Materials Science and Engineering, Shandong Key Laboratory of Special Epoxy Resin, Shandong University of Science and Technology Qingdao 266590 China znliu@sdust.edu.cn xueqz@upc.edu.cn jiantian@sdust.edu.cn.

Chemical science
|March 16, 2026
PubMed
概括

铜-酸盐金属-有机框架 (MOFs) 中的多态性影响了催化活性. 与它的α-Cu(Pz) 2多态相比, cis 配置的β-Cu(Pz) 2 MOF显著提高了酸盐还原反应的效率.

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For transition metal complexes, the coordination number determines the geometry around the central metal ion. Table 1 compares coordination numbers to molecular geometry. The most common structures of the complexes in coordination compounds are octahedral, tetrahedral, and square planar.
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