使用表面活性离子液体提高基于SiO2的纳米流体稳定性和热物理性质
Elaheh Janbezar1, Hemayat Shekaari2, Mohammed Taghi Zafarani-Moattar1
1Department of Physical Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, 5166616471, Iran.
Discover nano
|March 17, 2026
概括
表面活性离子液体 (SAIL) 增强了二氧化 (SiO2) 纳米流体的稳定性. 三2-基乙氨酸 (THEA-Ole) 为SiO2纳米颗粒提供了超过60天的优越的长期体稳定性.
科学领域:
- 材料科学 材料科学 材料科学
- 合体和表面化学
- 纳米技术 纳米技术
背景情况:
- 在二氧化 (SiO2) 纳米流体中实现长期的合稳定性对于其实际应用至关重要.
- 传统的表面活性剂通常提供有限的稳定性 (少于20天).
研究的目的:
- 研究特定表面活性离子液 (SAIL) 对水性SiO2纳米粒子分散物的稳定作用.
- 为了评估 (2-乙烯) 氨基酸盐 (HEA-Ole), bis(2-乙烯) 氨基酸盐 (BHEA-Ole) 和 tris(2-乙烯) 氨基酸盐 (THEA-Ole) 在提高SiO2稳定性的性能.
主要方法:
- 通过过多的摩尔体积,粘度,密度,动态光散射 (DLS),泽塔潜力,表面张力和60天的视觉观察来评估稳定性.
- 使用Eyring-mNRF和Eyring-NRTL方程对粘度进行建模.
- 使用Redlich-Kister,多项式,Ott和PC-SAFT模型的合适密度数据.
- 使用COSMO结果和PC-SAFT用于平均相对偏差 (ARD%) 的相互作用分析.
主要成果:
- 三二乙氨酸 (THEA-Ole) 显示出优异的SiO2纳米颗粒稳定性,特别是在临界菌度 (CMC) 以上.
- 泰油导致了最小的沉积,最佳的分散 (通过DLS) 和高的泽塔潜力.
- 粘度,多余摩尔体积和表面张力测量表明THEA-Ole纳米流体的趋势稳定.
- PC-SAFT建模证实了与THEA-Ole强烈的SiO2相互作用,显示了最低的ARD%.
结论:
- THEA-Ole为SiO2纳米流体提供了特殊的合体稳定性,超过60天.
- 这种SAIL显著优于传统的表面活性剂,解决了扩展应用中纳米流体分散的局限性.
- 这些发现为在各种技术领域更广泛地利用SiO2纳米流体铺平了道路.
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