水是酸盐玻璃中密集的类似冰的成分
1P. Richet, Laboratoire de Physique des Geomateriaux, Unite de Recherche Associee CNRS 734, Institut de Physique du Globe, 4, Place Jussieu, 75252 Paris Cedex 05, France. A. Polian, Laboratoire de Physique des Milieux Condenses, Unite de.
概括
在石玻璃中溶解的水,无论是基离子还是分子,具有与密度冰 VII.类似的特性. 这表明结驱动溶解,而不是体积变化,高含水量降低剪切模量.
科学领域:
- 地质化学 地质化学
- 材料科学 材料科学 材料科学
- 矿物物理 矿物物理
背景情况:
- 了解水在地质材料中的行为对于解释地球的过程至关重要.
- 酸盐玻璃中的水的溶解机制和物理效应尚未完全理解.
- 安德西特玻璃作为研究岩性质的模型系统.
研究的目的:
- 为了研究在石玻璃中溶解的水的物理性质.
- 为了确定石玻璃中水的部分摩尔体积和散装模量.
- 探索水的物种化,结合和玻璃特性之间的关系.
主要方法:
- 在环境条件下测量密度.
- 光散射光谱法用于探测声学特性.
- 在玻璃结构中分析水的物种化 (基与分子).
主要成果:
- 溶解的水表现出一个度独立的部分摩尔体积为12±0.5cm3/mol.
- 溶解水的散体模量为18 ± 3 GPa,与冰 VII.相比.
- 水的物种化是由控制的,而不是系统体积,在1重%以上的水中,剪切模量有显著的减少.
结论:
- 结合是石玻璃中水溶解的一个关键因素.
- 水在玻璃中的行为类似于冰VII的行为,表明类似的结构秩序.
- 高水度显著削弱了酸盐玻璃的机械完整性.
相关概念视频
States of Water
Water exists in any one of the three classical states: solid (ice), liquid (water), and gas (steam or water vapor). The state of water depends on i) the intermolecular forces that draw molecules together and ii) the kinetic energy that leads to movements that pull them apart.
Water freezes when the intermolecular forces are greater than the kinetic energy. Unlike most other substances, water is less dense in its solid state than in its liquid state. This is because each water molecule can form...
Water freezes when the intermolecular forces are greater than the kinetic energy. Unlike most other substances, water is less dense in its solid state than in its liquid state. This is because each water molecule can form...
Molecular and Ionic Solids
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
Solubility Equilibria: Ionic Product of Water
Pure water is a weak electrolyte; only a small amount ionizes into hydrogen and hydroxide ions. At any given temperature, the concentration of undissociated water is almost constant, so the ionic product of water is the product of the hydrogen and hydroxide ion concentrations, denoted as Kw. The square root of Kw gives the individual ion concentrations.
The ionic product of water varies with temperature, and its value is 1.0 x 10−14 at standard experimental conditions. Per Le Chatelier's...
The ionic product of water varies with temperature, and its value is 1.0 x 10−14 at standard experimental conditions. Per Le Chatelier's...
Washing, Drying, and Ignition of Precipitates
After filtration, the precipitate is washed to remove coprecipitated impurities and any remaining mother liquor. Colloidal precipitates, such as silver chloride, are washed with an electrolyte (such as dilute nitric acid) to prevent the peptization of the precipitate. In the case of slightly soluble precipitates, the wash solution contains a common ion to reduce solubility. Lead sulfate, which is slightly soluble in water, is washed with dilute sulfuric acid. Similarly, wash solutions may be...
Liquid–Solid Solutions
The process of a solid dissolving in a liquid to form a solution is governed by the solubility limit, which is the maximum amount of the solid substance, or solute, that can be dissolved in a specific volume of the liquid or solvent. As the solute dissolves, it reaches a point where no more solute can be dissolved at a given temperature - this is known as the saturation point. However, if further solute is added and it manages to dissolve, the solution becomes supersaturated. Supersaturated...
Unsoundness of Aggregate due to Volume Change
Unsoundness in aggregates due to volume changes is primarily caused by the physical alterations aggregates undergo, such as freezing and thawing, thermal changes, and wetting and drying. Unsound aggregates, when subjected to these changes, result in volume change upon disintegration. This, in turn, contributes to the deterioration of concrete, including scaling, pop-outs, and cracking. Particular types of aggregates, such as porous flints, cherts, and those containing clay minerals, are...


