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Updated: Jul 29, 2026

Synthesis of Nine-atom Deltahedral Zintl Ions of Germanium and their Functionalization with Organic Groups
08:15

Synthesis of Nine-atom Deltahedral Zintl Ions of Germanium and their Functionalization with Organic Groups

Published on: February 11, 2012

用单一来源的分子前体低温合成intl化合物

Beswick1, Choi, Harmer

  • 1M. A. Beswick, C. N. Harmer, A. D. Hopkins, D. S. Wright, Department of Chemistry, Lensfield Road, Cambridge CB2 1EW, UK. N. Choi and M. McPartlin, School of Chemistry, University of North London, London N7 8DB, UK.

Science (New York, N.Y.)
|September 4, 1998
PubMed
概括

一种新的异金属胺复合物作为一个稳定的,单一来源的Zintl化合物的前体. 这一发现为光活性金属反酸盐和其他先进材料提供了低温通路.

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Ziegler–Natta polymerization is another form of addition or chain‐growth polymerization used for synthesizing linear polymers over branched polymers. The catalyst used for polymerization is the Ziegler–Natta catalyst, named after Karl Ziegler and Giulio Natta, who developed it in 1953. This catalyst is an organometallic complex of titanium tetrachloride and triethyl aluminum, with the active form of the catalyst being an alkyl titanium compound. Using the Ziegler–Natta catalyst, high molecular...