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A New Expression for Multidimensional Franck-Condon Integrals
1Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei, Taiwan, 106, The Republic of China
Journal of Molecular Spectroscopy
|May 18, 1999
Abstract:
A new closed form expression for the Franck-Condon integrals for overlap between arbitrary multidimensional harmonic oscillators has been exactly derived by employing the generating functions method. The calculations lead to the deduction of some general rules whereby an arbitrary multidimensional Franck-Condon integral can be expressed as sums of products of the Hermite polynomials. Copyright 1999 Academic Press.