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Evaluating peats for their capacities to remove odorous compounds from liquid swine manure using headspace
A M Rizzuti1, A D Cohen, P G Hunt
1Department of Geological Sciences, University of South Carolina, Columbia 29208, USA.
Summary
Different peat types effectively remove odor-causing compounds from liquid swine manure (LSM). Peats with lower bulk density and higher water holding capacity were most effective at odor remediation.
Area of Science:
- Environmental Science
- Agricultural Science
- Analytical Chemistry
Background:
- Liquid swine manure (LSM) produces strong odors, necessitating effective remediation strategies.
- Peat, a natural organic material, has shown potential for adsorbing odorous compounds.
- Understanding the specific properties of peat that enhance odor removal is crucial for developing efficient treatment methods.
Purpose of the Study:
- To investigate the efficacy of various characterized peat types in removing odor-causing compounds from LSM.
- To identify key chemical and physical properties of peat that correlate with superior odor remediation capabilities.
Main Methods:
- Preparation of 8% peat/LSM slurries.
- Odor assessment after 24 hours using sensory odor panels.
- Chemical analysis of volatile compounds using Gas Chromatography/Mass Spectrometry-Solid Phase Microextraction (GC/MS-SPME).
Main Results:
- All tested peat types demonstrated effectiveness in reducing LSM odors.
- Certain peat types exhibited superior odor removal performance compared to others.
- Effective peats generally had lower bulk density, ash, fulvic acid, and guaiacyl lignin content.
- Higher water holding capacity, hydraulic conductivity, "total other lignins", hydrogen, carbon, and cellulose content were associated with better odor removal.
Conclusions:
- Peat is a viable material for mitigating odors associated with liquid swine manure.
- Specific peat properties, including low bulk density and high water retention, are indicative of enhanced odor removal efficiency.
- GC/MS-SPME is a cost-effective and precise analytical method for evaluating peat efficacy in odor remediation research.