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[In]

von Hänisch C1, Fenske, Kattannek

  • 1Institut für Nanotechnologie, Forschungszentrum Karlsruhe GmbH, D-76021 Karlsruhe (Germany).

Angewandte Chemie (International Ed. in English)
|October 3, 1999
PubMed
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A novel 19-atom indium-phosphorus (In-P) polyhedron with near C(3) symmetry was synthesized. This unique cluster features In-P, In-In, and P-P bonds, forming a core structure with surrounding ligands.

Area of Science:

  • Inorganic Chemistry
  • Materials Science
  • Cluster Chemistry

Background:

  • Indium-phosphorus compounds are of interest due to their unique bonding and structural properties.
  • The synthesis of novel cluster compounds provides insights into chemical bonding and reactivity.

Purpose of the Study:

  • To synthesize and characterize a novel indium-phosphorus cluster compound.
  • To investigate the structural features and bonding within the cluster core.

Main Methods:

  • Synthesis via the reaction of indium(III) chloride (InCl3) with triethylphosphine (PEt3) and phenylbis(trimethylsilyl)phosphine (PhP(SiMe3)2).
  • Structural analysis of the resulting 19-atom In-P polyhedron.

Main Results:

  • A novel 19-atom In-P polyhedron with near C(3) symmetry was successfully synthesized.

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  • The cluster core exhibits a unique structure containing indium-phosphorus (In-P), indium-indium (In-In), and phosphorus-phosphorus (P-P) bonds.
  • The cluster is further stabilized by six terminal chloro ligands and three triethylphosphine (PEt3) ligands, enclosing a central chloride anion.

    • Conclusions:

    • The synthesized compound represents a new structural motif in indium-phosphorus chemistry.
    • The presence of multiple bond types (In-P, In-In, P-P) within the cluster highlights complex bonding interactions.
    • This discovery expands the known structural diversity of indium-based clusters.