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Enantioselective ring opening of meso aziridines catalyzed by Tridentate Schiff base chromium(III) complexes
Z Li1, M Fernández, E N Jacobsen
1Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, USA.
Organic Letters
|June 3, 2000
Abstract:
[formula: see text] A catalytic method for the enantioselective ring opening of meso aziridines by TMSN3 is described. Tridentate Schiff base chromium complexes derived from 1-amino-2-indanol were identified as the optimal catalysts.