210Pb and 210Po determination in environmental samples

Sequential separation of 210Pb and 21OPo in environmental samples allows the determination of these naturally occurring radionuclides with good chemical yields and low detection limits. After sample mineralization, part of the leaching solution is used for 210Po determination which does not require any further treatment and essentially quantitative recoveries are obtained, using a standard 209Po tracer. The remaining part of the leaching solution is used for 210Pb determination. Starting from 3 g sediment (30 l water), the lower limits of detection of the method are 1.4 Bq kg(-1) (0.14 mBq l(-1)) for 210Pb and 0.25 Bq kg(-1) (0.016 mBq l(-1)) for 21OPo. The procedure has been checked by analysing two certified reference materials, supplied by IAEA, and reliable results have been obtained.