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Related Concept Videos

UV–Vis Spectroscopy of Conjugated Systems01:32

UV–Vis Spectroscopy of Conjugated Systems

Organic compounds with conjugated double bonds show strong absorption features in the UV–visible region of the electromagnetic spectrum attributed to π → π* electronic excitations. Generally, a UV–vis absorption spectrum is recorded as a plot of absorbance vs wavelength. The wavelength of maximum absorbance, which manifests as a peak in the absorption spectrum, is denoted as λmax.
One of the factors influencing λmax is the extent of conjugation in the...
¹³C NMR: ¹H–¹³C Decoupling01:04

¹³C NMR: ¹H–¹³C Decoupling

The probability of having two carbon-13 atoms next to each other is negligible because of the low natural abundance of carbon-13. Consequently, peak splitting due to carbon-carbon spin-spin coupling is not observed in spectra. However, protons up to three sigma bonds away split the carbon signal according to the n+1 rule, resulting in complicated spectra.
A broadband decoupling technique is used to simplify these complex, sometimes overlapping, signals. Broadband decoupling relies on a...
UV–Vis Spectroscopy: Woodward–Fieser Rules01:29

UV–Vis Spectroscopy: Woodward–Fieser Rules

UV–Visible absorption spectra of conjugated dienes arise from the lowest energy π → π* transitions. The light-absorbing part of the molecule is called the chromophore, and the substituents directly attached to the chromophore are called auxochromes. A strong correlation exists between the absorption maxima, λmax, and the structure of a conjugated π system. The Woodward–Fieser rules predict the value of λmax for a given structure by adding the contributions...
Superconductor01:24

Superconductor

A substance that reaches superconductivity, a state in which magnetic fields cannot penetrate, and there is no electrical resistance, is referred to as a superconductor. In 1911, Heike Kamerlingh Onnes of Leiden University, a Dutch physicist, observed a relation between the temperature and the resistance of the element mercury. The mercury sample was then cooled in liquid helium to study the linear dependence of resistance on temperature. It was observed that, as the temperature decreased, the...
Types Of Superconductors01:28

Types Of Superconductors

A superconductor is a substance that offers zero resistance to the electric current when it drops below a critical temperature. Zero resistance is not the only interesting phenomenon as materials reach their transition temperatures. A second effect is the exclusion of magnetic fields. This is known as the Meissner effect. A light, permanent magnet placed over a superconducting sample will levitate in a stable position above the superconductor. High-speed trains that levitate on strong...
Theory of Metallic Conduction01:17

Theory of Metallic Conduction

The conduction of free electrons inside a conductor is best described by quantum mechanics. However, a classical model makes predictions close to the results of quantum mechanics. It is called the theory of metallic conduction.
In this theory, Newton's second law of motion is used to determine the acceleration of an electron in the presence of an applied electric field. Then, its velocity is expressed via this acceleration.
An electron moves through the crystal, containing positive ions,...

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Updated: Jul 25, 2026

Angle-resolved Photoemission Spectroscopy At Ultra-low Temperatures
08:53

Angle-resolved Photoemission Spectroscopy At Ultra-low Temperatures

Published on: October 9, 2012

Spectroscopic evidence for unconventional superconductivity in UBe13

Walti1, Ott, Fisk

  • 1Laboratorium fur Festkorperphysik, ETH-Honggerberg, 8093 Zurich, Switzerland.

Physical Review Letters
|September 16, 2000
PubMed
Summary

Measurements of UBe13-Au contacts reveal low-energy Andreev surface bound states, indicating strong coupling effects in this superconductor. These findings are crucial for understanding unconventional superconductivity.

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Last Updated: Jul 25, 2026

Angle-resolved Photoemission Spectroscopy At Ultra-low Temperatures
08:53

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Published on: October 9, 2012

Visualizing Uniaxial-strain Manipulation of Antiferromagnetic Domains in Fe1+YTe Using a Spin-polarized Scanning Tunneling Microscope
09:06

Visualizing Uniaxial-strain Manipulation of Antiferromagnetic Domains in Fe1+YTe Using a Spin-polarized Scanning Tunneling Microscope

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Comparison of Two Different Synthesis Methods of Single Crystals of Superconducting Uranium Ditelluride
04:51

Comparison of Two Different Synthesis Methods of Single Crystals of Superconducting Uranium Ditelluride

Published on: July 8, 2021

Area of Science:

  • Condensed Matter Physics
  • Materials Science
  • Superconductivity

Background:

  • Uranium beryllium (UBe13) is a heavy fermion superconductor.
  • Understanding the nature of its superconducting state, particularly the energy gap, is crucial.

Purpose of the Study:

  • To investigate the superconducting properties of UBe13-Au contacts.
  • To identify the presence and characteristics of low-energy bound states.

Main Methods:

  • Differential conductivity (G) measurements of UBe13-Au contacts.
  • Analysis of the voltage dependence of conductivity at temperatures below the critical temperature (T < Tc).

Main Results:

  • Observed huge conductance peaks at zero bias, indicative of low-energy Andreev surface bound states.
  • Established a lower limit for the normalized energy gap: 2Δ(0) / kBTc > 6.7.
  • These results significantly exceed the Bardeen-Cooper-Schrieffer (BCS) weak coupling value of 3.5.

Conclusions:

  • The presence of Andreev surface bound states confirms nontrivial energy-gap functions in UBe13.
  • The large normalized energy gap strongly suggests strong coupling effects in superconducting UBe13.
  • These findings contribute to the understanding of unconventional superconductivity in heavy fermion systems.