Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

Multi-Step Reactions02:31

Multi-Step Reactions

Chemical reactions often occur in a stepwise fashion involving two or more distinct reactions taking place in a sequence. A balanced equation indicates the reacting species and the product species, but it reveals no details about how the reaction occurs at the molecular level. The reaction mechanism (or reaction path) provides details regarding the precise, step-by-step process by which a reaction occurs. Each of the steps in a reaction mechanism is called an elementary reaction. These...
Predicting Reaction Outcomes02:24

Predicting Reaction Outcomes

Kinetics describes the rate and path by which a reaction occurs. In contrast, thermodynamics deals with state functions and describes the properties, behavior, and components of a system. It is not concerned with the path taken by the process and cannot address the rate at which a reaction occurs. Although it does provide information about what can happen during a reaction process, it does not describe the detailed steps of what appears on an atomic or a molecular level. On the other hand,...
SN2 Reaction: Kinetics02:14

SN2 Reaction: Kinetics

Kinetic Studies and Significance
In a chemical reaction, a relationship exists between the concentration of reactants and the rate at which the reaction proceeds. The study to measure this relationship is known as the kinetics of a chemical reaction. Kinetic studies are used to deduce the rate law of a chemical reaction, which provides information about the species involved during the transition state of the rate-determining step. Thus, kinetic studies help to derive the mechanism of a reaction.
SN1 Reaction: Kinetics02:05

SN1 Reaction: Kinetics

In an SN2 reaction, the reaction rate depends on both the type of nucleophile and the substrate. A hindered tertiary alkyl halide is practically inert to the SN2 mechanism despite using a strong nucleophile.
However, Sir Christopher Ingold and Edward D. Hughes, who studied the kinetics of various nucleophilic substitution reactions, noticed that a tertiary alkyl halide does undergo a nucleophilic substitution reaction in the presence of a weak nucleophile. While studying the substitution...
Interfacial Electrochemical Methods: Overview01:06

Interfacial Electrochemical Methods: Overview

Interfacial electrochemical methods focus on the phenomena occurring at the boundary between an electrode and a solution, as opposed to bulk methods that concentrate on the solution's overall properties. These interfacial methods are classified as either static or dynamic based on the presence of a nonzero current in the electrochemical cell and the consistency of analyte concentrations. Static methods, such as potentiometry, measure the cell's potential without any significant current passing...
Heterogeneous Catalysis01:22

Heterogeneous Catalysis

Heterogeneous catalysis involves a catalyst in a different phase from the reactants. It is a process where the catalyst and the reactants are in distinct phases, typically solid and gas or liquid.Most heterogeneous catalysts are metals, metal oxides, or acids. The list includes transition metals like iron (Fe), cobalt (Co), nickel (Ni), palladium (Pd), platinum (Pt), chromium (Cr), manganese (Mn), tungsten (W), silver (Ag), and copper (Cu). These metals possess partially vacant d orbitals that...

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

An assessment of quality control testing in an emergency department (ED) maintained arterial blood gas analyzer

Academic emergency medicine : official journal of the Society for Academic Emergency Medicine·2000
Same author

Search for D0D-bar0 Mixing in Semileptonic Decay Modes.

Physical review letters·1996
Same author

Polymer reaction kinetics at interfaces.

Physical review letters·1996
Same author

Search for the flavor-changing neutral-current decays D+--> pi + micro+ micro- and D+--> pi +e+e-

Physical review letters·1996
Same author

Rheology of wormlike Micelles: Two universality classes.

Physical review letters·1995
Same author

Anomalous diffusion at liquid surfaces.

Physical review letters·1995

Related Experiment Video

Updated: Jul 13, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
11:44

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 21, 2014

Interfacial reactions: mixed order kinetics and segregation effects

O'Shaughnessy1, Vavylonis

  • 1Department of Chemical Engineering, Columbia University, New York, New York 10027, USA.

Physical Review Letters
|October 6, 2000
PubMed
Summary

This study reveals reaction kinetics at interfaces. Below a critical dimension, anomalous decay and segregation occur, deviating from standard mean-field theory predictions.

Area of Science:

  • Physical Chemistry
  • Chemical Kinetics
  • Interfacial Phenomena

Background:

  • Reaction kinetics at interfaces are crucial for many chemical and physical processes.
  • Understanding the influence of dimensionality on reaction dynamics is essential.
  • Mean-field theory often fails to capture complex behaviors in lower dimensions.

Purpose of the Study:

  • To investigate the kinetics of A-B reactions at a fixed interface.
  • To explore the transition from second-order to first-order kinetics.
  • To identify and characterize a new kinetic regime below a critical dimension.

Main Methods:

  • Theoretical analysis of reaction kinetics.
  • Derivation of scaling laws for reaction rates.
  • Numerical simulations to validate theoretical predictions.

More Related Videos

Unraveling Entropic Rate Acceleration Induced by Solvent Dynamics in Membrane Enzymes
09:42

Unraveling Entropic Rate Acceleration Induced by Solvent Dynamics in Membrane Enzymes

Published on: January 16, 2016

Reaction Kinetics and Combustion Dynamics of I4O9 and Aluminum Mixtures
09:16

Reaction Kinetics and Combustion Dynamics of I4O9 and Aluminum Mixtures

Published on: November 7, 2016

Related Experiment Videos

Last Updated: Jul 13, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
11:44

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 21, 2014

Unraveling Entropic Rate Acceleration Induced by Solvent Dynamics in Membrane Enzymes
09:42

Unraveling Entropic Rate Acceleration Induced by Solvent Dynamics in Membrane Enzymes

Published on: January 16, 2016

Reaction Kinetics and Combustion Dynamics of I4O9 and Aluminum Mixtures
09:16

Reaction Kinetics and Combustion Dynamics of I4O9 and Aluminum Mixtures

Published on: November 7, 2016

Main Results:

  • Initial second-order kinetics depend on far-field densities.
  • Long-time first-order kinetics are governed by diffusion and molecular displacement.
  • A novel regime emerges below critical dimension d

Conclusions:

  • The study elucidates distinct kinetic regimes based on dimensionality.
  • Anomalous interfacial density decay and segregation are observed in lower dimensions.
  • Numerical simulations confirm the theoretical framework for z=2.