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Chloramine-B sesquihydrate.

E George1, S Vivekanandan, K Sivakumar

  • 1Department of Chemistry, Pachaiyappa's College, Chennai 600 030, India.

Acta Crystallographica. Section C, Crystal Structure Communications
|October 12, 2000
PubMed
Summary
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Sodium N-chlorobenzenesulfonamide sesquihydrate forms a 2D polymeric layer through octahedral coordination. Water molecules link these layers via extensive hydrogen bonding, influencing crystal structure.

Area of Science:

  • Inorganic Chemistry
  • Crystallography
  • Supramolecular Chemistry

Background:

  • Understanding the coordination chemistry and crystal packing of metal-organic compounds is crucial for materials science.
  • Sodium N-chlorobenzenesulfonamide sesquihydrate is a specific salt with potential applications in chemical synthesis or as a material component.

Purpose of the Study:

  • To elucidate the crystal structure and coordination environment of sodium N-chlorobenzenesulfonamide sesquihydrate.
  • To characterize the hydrogen bonding network and its role in the overall structure.

Main Methods:

  • Single-crystal X-ray diffraction was employed to determine the atomic arrangement.
  • Analysis of coordination geometry and hydrogen bond distances/angles was performed.

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Main Results:

  • The sodium ion is octahedrally coordinated by water oxygens and sulfonamide oxygens, forming a 2D polymeric layer.
  • The crystal structure features face-sharing octahedra linked into a layered network parallel to the ab plane.
  • Water molecules act as hydrogen bond donors and acceptors, connecting the layers via O-H...O, O-H...N, and O-H...Cl interactions.

Conclusions:

  • The compound exhibits a unique 2D layered structure driven by coordination and hydrogen bonding.
  • The detailed structural analysis provides insights into the self-assembly of inorganic-organic hybrid materials.