Related Experiment Video
Updated: Oct 10, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
Palladium-mediated formation of bowl-shaped PAHs: synthesis of as-Indaceno
Abstract:
Bowl-shaped fullerene fragments, as-indaceno[3,2,1,8,7, 6-pqrstuv]picenes, can be synthesized by a double palladium-mediated cyclization in good to excellent yield. The structure of 1, 8-dimethyl as-indaceno[3,2,1,8,7,6-pqrstuv]picene was confirmed by X-ray analysis. The high yields, mild reaction conditions, and wide range of functional group tolerance are advantages of this method over existing FVP and reductive coupling routes to bowl-shaped PAHs.
More Related Videos
11:44Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
Published on: March 20, 2014
09:22Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
Published on: February 7, 2017