Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Videos

2,2,4,4-Tetramethyl-1,5-diphenyl-6,7,8-trioxa-3-thiabicyclo

Cuthbertson1, Frampton, MacNicol

  • 1Department of Chemistry, University of Glasgow, Glasgow G12 8QQ, Scotland.

Acta Crystallographica. Section C, Crystal Structure Communications
|December 19, 2000
PubMed
Summary
This summary is machine-generated.

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Lymphatic Mapping for Melanoma: Long-term Results of Regional Nodal Sampling With Radioguided Surgery.

Cancer control : journal of the Moffitt Cancer Center·2000
Same author

Elusive Z' coupled to quarks of third generation.

Physical review. D, Particles and fields·1996
Same author

Horizontal Symmetry for Quark and Squark Masses in Supersymmetric SU(5).

Physical review letters·1996
Same author

Effective Lagrangians and parity-conserving time-reversal violation at low energies.

Physical review. D, Particles and fields·1996
Same author

Dicyclic horizontal symmetry and supersymmetric grand unification.

Physical review. D, Particles and fields·1996
Same author

Dilepton Production in High Luminosity Multi-GeV Electron Scattering.

Physical review letters·1995

The crystal structure of a title ozonide (C20H22O3S) was determined without ozone. Its ozonide and 1,4-oxathiane rings adopt specific conformations, revealing key structural details.

Area of Science:

  • Crystallography
  • Organic Chemistry
  • Molecular Structure

Background:

  • Ozonides are a class of organic compounds containing the O-O bond.
  • Understanding the structural properties of ozonides is crucial for their synthesis and reactivity studies.
  • The title ozonide, C20H22O3S, was synthesized without direct ozone application.

Purpose of the Study:

  • To elucidate the three-dimensional molecular structure of the title ozonide.
  • To determine the conformation of the ozonide and 1,4-oxathiane rings within the crystal lattice.
  • To provide precise bond length and torsion angle data for the ozonide functional group.

Main Methods:

  • Single-crystal X-ray diffraction analysis.
  • Structure determination at low temperature (123(1) K).

Related Experiment Videos

  • Analysis of molecular symmetry and ring conformations.

    • Main Results:

    • The crystal structure of C20H22O3S was successfully determined in the triclinic crystal system.
    • The molecule exhibits approximate Cs symmetry.
    • The ozonide ring adopts an envelope conformation, while the 1,4-oxathiane ring adopts a chair conformation.

    Conclusions:

    • The study provides the first crystallographic data for this specific title ozonide.
    • The determined O-O bond length is 1.4721 (12) Å, and the C-O-O-C torsion angle is -1.45 (12) degrees.
    • The conformational analysis offers insights into the stereochemistry of ozonides and related heterocyclic systems.