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[5,10,15,20-Tetrakis(2-thienyl)-porphyrinato]zinc(II)
B Purushothaman1, B Varghese, P Bhyrappa
1Department of Chemistry, Indian Institute of Technology -- Madras, Chennai 600 036, India.
Abstract:
In the title complex, [Zn(C(36)H(20)N(4)S(4))], the Zn(II) ion occupies a special position on an inversion centre with four-coordinate geometry. The porphyrin ring shows a wave-like conformation, with the closest interporphyrin plane separation being 3.60 (6) A. The two disordered thienyl groups are inclined with respect to the porphyrin plane at angles of 70 (4) and 67 (2) degrees.