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Barium oxoaluminate hydride
1Institut für Anorganische und Analytische Chemie, Universität Freiburg, Albertstrasse 21, D-79104 Freiburg, Germany.
Abstract:
The crystal structure of Ba(3)(AlO(4))H is isotypic with Ba(3)SiS(5) and contains AlO(4)(5-) and H(-) anions. The hydride and oxide anions are coordinated by six Ba and five Ba/one Al atoms in an octahedral geometry. The hydrogen content was examined by MAS-NMR experiments of the deuterated compound.