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A free radical.

A Carrington1

  • 1Department of Chemistry, University of Southampton, Hampshire SO17 1BJ, England. ac@soton.ac.uk

Annual Review of Physical Chemistry
|April 28, 2001
PubMed
Summary
This summary is machine-generated.

This research career spans decades of spectroscopy, focusing on electronic spin resonance (ESR) and microwave magnetic resonance (MMR) of transition metal complexes, free radicals, and molecular ions. The work advanced understanding of molecular structures and spectra.

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Area of Science:

  • Physical Chemistry
  • Spectroscopy
  • Chemical Physics

Background:

  • Research career from 1955-2000.
  • Initial work on electronic structure and spectra of transition metal complexes.
  • Studies included electronic spin resonance (ESR) of single crystals.

Purpose of the Study:

  • To detail a research career focused on spectroscopy.
  • To explore the evolution of techniques in studying molecular species.
  • To document advancements in understanding free radicals and molecular ions.

Main Methods:

  • Employed electronic spin resonance (ESR) spectroscopy.
  • Utilized microwave magnetic resonance (MMR) spectroscopy.
  • Applied ion beam methods for gas-phase molecular ion studies.

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Main Results:

  • Investigated ESR spectra of transition metal complexes and liquid-phase organic free radicals.
  • Analyzed MMR spectra of gaseous free radicals.
  • Studied gas-phase molecular ions (e.g., H(+)2, HD(+), H(+)3) and high-energy levels near dissociation.

Conclusions:

  • Significant contributions to the field of molecular spectroscopy over a 45-year career.
  • Pioneered techniques for studying free radicals and molecular ions.
  • Advanced the understanding of electronic structures and spectral analysis.