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In situ oxidation-imine formation-reduction routes from alcohols to amines
1Department of Chemistry, University of York, Heslington, York, YO10 5DD, UK.
Organic Letters
|June 19, 2001
Abstract:
Manganese dioxide is employed as an in situ oxidant for the one-pot conversion of alcohols into imines. In combination with polymer-supported cyanoborohydride (PSCBH), a one-pot oxidation-imine formation-reduction sequence is reported. This procedure enables alcohols to be converted directly into both secondary and tertiary amines.