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Toxicity of organotin compounds to activated sludge
A S Stasinakis1, N S Thomaidis, T D Lekkas
1Laboratory of Water and Air Quality, Department of Environmental Studies, University of the Aegean, 17 Karadoni str., 81100 Mytilene, Greece. astas@env.aegean.gr
Abstract:
Inhibition of respiration rate of activated sludge heterotrophic microorganisms was determined for tributyltin (TBT), dibutyltin (DBT), monobutyltin (MBT), and triphenyltin (TPhT). TBT, DBT, and TPhT exhibit similar acute toxicity to activated sludge, while MBT is less toxic. The effect of various experimental parameters, such as sludge age, concentrations of suspended solids, and exposure time, on toxicity was investigated. An increase in sludge age or in the concentration of suspended solids reduces the observed inibition. Longer exposure seems to increase the inhibition of TBT, DBT, and TPhT during the first hours of exposure, while later the inhibition remains constant. In the case of MBT, 24 h after exposure, the respiration rate was similar to that of the control biomass.