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Reaction of D-glycals with azidotrimethylsilane
H Kawabata1, S Kubo, M Hayashi
1Department of Chemistry, Faculty of Science, Yamaguchi University, Yamaguchi 753-8512, Japan.
Carbohydrate Research
|July 13, 2001
Abstract:
The treatment of 2,3,4,6-tetra-O-acetyl-1,5-anhydro-D-arabino-hex-1-enitol with azidotrimethylsilane by the aid of a catalytic amount of Yb(OTf)(3) afforded 2,4,6-tri-O-acetyl-2,3-dideoxy-alpha-D-erythro-hex-2-enopyranosyl azide in high yield.