Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Videos

Solid-phase organometallic synthesis.

K Heinze1

  • 1Anorganisch-chemisches Institut der Universität Heidelberg, Germany. katja@sun0.urz.uni-heidelberg.de

Chemistry (Weinheim an Der Bergstrasse, Germany)
|August 7, 2001
PubMed
Summary
This summary is machine-generated.

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Stress transmission in cemented bidisperse granular materials.

Physical review. E·2020
Same author

Intrinsic superoxide dismutase activity of MnO nanoparticles enhances the magnetic resonance imaging contrast.

Journal of materials chemistry. B·2020
Same author

On the effect of local sample slope during modulus measurements by contact-resonance atomic force microscopy.

Ultramicroscopy·2018
Same author

Protein Nanocontainers from Nonviral Origin: Testing the Mechanics of Artificial and Natural Protein Cages by AFM.

The journal of physical chemistry. B·2016
Same author

[Neuromodulation - new techniques].

Der Urologe. Ausg. A·2015
Same author

Comparative pilot study of implantation techniques for pudendal neuromodulation: technical and clinical outcome in first 20 patients with chronic pelvic pain.

World journal of urology·2014
Same journal

Harnessing Naphthalimide Scaffolds for Sustainable CO<sub>2</sub> Utilization: A Metal-, Halide-, and Solvent-Free Photocatalytic CO<sub>2</sub> Cycloaddition via Sequential Two-Photon Activation.

Chemistry (Weinheim an der Bergstrasse, Germany)·2026
Same journal

Protein-Independent Liquid-Liquid Phase Separation of Adenosine Triphosphate Under Crowded Conditions.

Chemistry (Weinheim an der Bergstrasse, Germany)·2026
Same journal

A Unified Approach for the Synthesis of Conformationally Locked and sp<sup>2</sup>-sp<sup>3</sup> Fused Hybrids.

Chemistry (Weinheim an der Bergstrasse, Germany)·2026
Same journal

Decoding Heptazine Architectures: From Molecular Association to Structural Insight.

Chemistry (Weinheim an der Bergstrasse, Germany)·2026
Same journal

An Electrophilic Uridine Building Block for Post-Synthetic RNA Modification as Exemplified for Spin Labeling.

Chemistry (Weinheim an der Bergstrasse, Germany)·2026
Same journal

Recent Advances in Pd-Catalyzed Directed meta-C-H Olefination: Strategies and Outlook.

Chemistry (Weinheim an der Bergstrasse, Germany)·2026
See all related articles

A novel solid-phase synthesis method enables molybdenum carbonyl complex preparation. This approach facilitates complexation, substitution, and elimination reactions on solid supports under mild conditions.

Area of Science:

  • Organometallic Chemistry
  • Solid-Phase Synthesis

Background:

  • Traditional synthesis of molybdenum carbonyl complexes often involves solution-phase reactions.
  • Solid-phase synthesis offers advantages in purification and automation for complex molecule preparation.

Purpose of the Study:

  • To develop a versatile solid-phase synthesis strategy for molybdenum carbonyl complexes.
  • To enable key organometallic reactions, including metal-complexation and ligand substitution, on a solid support.

Main Methods:

  • Development of a solid-phase system for molybdenum carbonyl complex synthesis.
  • Performing metal-complexation, ligand substitution, and oxidative elimination reactions on the solid phase.
  • Utilizing mild and selective cleavage conditions for the final product isolation.

Related Experiment Videos

Main Results:

  • Successful demonstration of a solid-phase approach for synthesizing molybdenum carbonyl complexes.
  • The system allows for sequential reactions including complexation, substitution, and elimination.
  • Mild cleavage conditions ensure the integrity of the synthesized complexes.

Conclusions:

  • The developed solid-phase synthesis is a viable and efficient alternative to traditional liquid-phase methods.
  • This method provides a platform for streamlined and potentially automated synthesis of molybdenum carbonyl compounds.
  • The approach offers advantages in handling and purification compared to solution-phase techniques.