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Updated: Aug 14, 2026

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
Published on: April 19, 2019
Hamigerin A and a hamigerin D decomposition product
R C Cambie1, C E Rickard, P S Rutledge
1Department of Chemistry, University of Auckland, Private Bag 92019, Auckland, New Zealand.
Abstract:
The sponge Hamigera tarangaensis has yielded eight new compounds and we report here the structure of one of these compounds, hamigeran A, C(20)H(25)BrO(5), or methyl 7-bromo-4beta,6-dihydroxy-1beta-isopropyl-3aalpha,8-dimethyl-5-oxo-1a,3a,4,5-tetrahydrocyclopenta[a]naphthalene-4-carboxylate, and the decomposition product of hamigeran D, C(21)H(28)BrNO(4), namely 2-(8-bromo-2beta,7-dimethyl-4-oxo-1,3alpha-benzoxazan-5-yl)-3-isopropylcyclopentylacetic acid.
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