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Related Experiment Videos

trans-1,2,3-Tris(1-hydroxycyclopropyl)cyclopropane.

D S Yufit1, J A Howard, S I Kozhushkov

  • 1Department of Chemistry, University of Durham, South Rd, Durham DH1 3LE, England. d.s.yufit@durham.ac.uk

Acta Crystallographica. Section C, Crystal Structure Communications
|August 11, 2001
PubMed
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The cyclopropane ring in trans-1,1

Area of Science:

  • Organic Chemistry
  • Crystallography

Background:

  • Cyclopropane rings are strained three-membered carbocycles with unique chemical properties.
  • Understanding substituent effects on cyclopropane geometry is crucial for predicting reactivity.

Purpose of the Study:

  • To investigate the structural characteristics of trans-1,1',1"-cyclopropane-1,2,3-triyltris(cyclopropanol).
  • To analyze the impact of multiple cyclopropanol substituents on the central cyclopropane ring's geometry.

Main Methods:

  • Single-crystal X-ray diffraction analysis was employed to determine the molecular structure.
  • Analysis of bond lengths and angles to quantify geometric distortions.

Main Results:

  • The central cyclopropane ring exhibits significant bond length asymmetry.

Related Experiment Videos

  • The orientation of the pendant cyclopropanol groups induces this distortion.
  • Intermolecular hydrogen bonding forms a sheet-like network in the crystal.

    • Conclusions:

    • The study reveals pronounced geometric asymmetry in a highly substituted cyclopropane.
    • Hydrogen bonding plays a key role in the supramolecular assembly of this compound.