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XAFS study on a pressure-induced superconductor Cs3C60 under high pressure
S Fujiki1, Y Kubozono, Y Takabayashi
1Okayama University, Japan. fuziki@cc.okayama-u.ac.jp
Journal of Synchrotron Radiation
|August 22, 2001
Abstract:
Cs K-edge XAFS of Cs3C60 which is a pressure-induced superconductor were measured at 21 and 34 kbar by using a diamond anvil cell (DAC) in order to obtain the structural information under high pressure, and to clarify the origin of the pressure-induced superconductivity. The distances and the mean square displacements between the Cs and C atoms are consistent with those determined by X-ray powder diffraction. Consequently, the high-pressure XAFS can give the reliable structural-information on a fullerene superconductor under high pressure. We also show the procedure of the analysis of high-pressure XAFS with DAC in detail.